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Research on combustion characteristics of bio-oil from sewage sludge

Rui LI, Baosheng JIN, Xiangru JIA, Zhaoping ZHONG, Gang XIAO, Xufeng FU

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 161-166 doi: 10.1007/s11705-009-0057-0

摘要： Combustion characteristics of bio-oil from sewage sludge were investigated using thermogravimetry (TG) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques. The combustion process could be divided into two weight loss stages. Light compounds volatilized and were oxidized in the first stage and the heterogeneous combustion between oxygen and heavy compounds happened in the second stage, which were confirmed by FT-IR technique. Most weight loss occurred in the first stage. The effect of heating rate was also studied and higher heating rates were found to facilitate the combustion process. The kinetic parameters of the two stages were calculated and the change of activation energy indicated higher heating rates benefited combustion.

关键词： bio-oil from sewage sludge     fast pyrolysis     combustion characteristics     TG-FT-IR     kinetic    

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Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 702-717 doi: 10.1007/s11705-019-1861-9

摘要： The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercritical conditions using methanol, ethanol and isopropanol as solvent and hydrogen donor. Characterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content, elemental content, pH, heating value, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared radiation, C nuclear magnetic resonance spectroscopy, and thermogravimetric analysis to evaluate the effects of blending and supercritical reactions. The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oil consequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanol reaction. The ester contents increased by 87.49% after the supercritical methanol reaction indicating ester formation could be the major deacidification mechanism for reducing the acidity of the bio-oil and improving its pH value. Simply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing the O content and increasing the heating value to 27.55 from 17.51 MJ·kg in the crude bio-oil. After the supercritical isopropanol reaction, the heating value of the liquid product slightly further increased to 28.85 MJ·kg .

关键词： bio-oil     blending     supercritical     upgrading     characterisation    

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生物油的蒸馏特性及其应用

杨续来,陆　强,朱锡锋

《中国工程科学》 2007年 第9卷 第11期   页码 110-114

摘要：

生物油常压馏分约占样品总量的50％，其余为结焦残余物，说明生物油不易蒸发燃烧，但可以雾化 燃烧；生物油成分复杂，其中由木质素衍生的酚类含量较为丰富，可采用减压蒸馏或蒸汽蒸馏进行分离提取； 蒸馏方法还可用于生物油的品质改良，如增强油品的稳定性、提高热值和降低pH值等。

关键词： 生物油     蒸馏     酚类     品质改良    

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Design of bio-oil additives via molecular signature descriptors using a multi-stage computer-aided molecular

《化学科学与工程前沿（英文）》 2022年 第16卷 第2期   页码 168-182 doi: 10.1007/s11705-021-2056-8

摘要： Direct application of bio-oil from fast pyrolysis as a fuel has remained a challenge due to its undesirable attributes such as low heating value, high viscosity, high corrosiveness and storage instability. Solvent addition is a simple method for circumventing these disadvantages to allow further processing and storage. In this work, computer-aided molecular design tools were developed to design optimal solvents to upgrade bio-oil whilst having low environmental impact. Firstly, target solvent requirements were translated into measurable physical properties. As different property prediction models consist different levels of structural information, molecular signature descriptor was used as a common platform to formulate the design problem. Because of the differences in the required structural information of different property prediction models, signatures of different heights were needed in formulating the design problem. Due to the combinatorial nature of higher-order signatures, the complexity of a computer-aided molecular design problem increases with the height of signatures. Thus, a multi-stage framework was developed by developing consistency rules that restrict the number of higher-order signatures. Finally, phase stability analysis was conducted to evaluate the stability of the solvent-oil blend. As a result, optimal solvents that improve the solvent-oil blend properties while displaying low environmental impact were identified.

关键词： computer-aided molecular design     bio-oil additives     molecular signature descriptor    

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A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第1期   页码 4-17 doi: 10.1007/s11705-020-1933-x

摘要： This review article summarizes the key published research on the topic of bio-oil upgrading using catalytic and non-catalytic supercritical fluid (SCF) conditions. The precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oil upgrading in SCFs. This is reportedly due to their favourable catalytic activity during the process including hydrotreating, hydrocracking, and esterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oil. Due to the costs associated with precious metal catalysts, some researchers have opted for non-precious metal catalysts such as acidic HZSM-5 which can promote esterification in supercritical ethanol. On the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst. Supercritical methanol, ethanol, and water are most commonly used and demonstrate catalyst like activities such as facilitating esterification reactions and reducing solid yield by alcoholysis and hydrolysis, respectively.

关键词： bio-oil     upgrading     supercritical     review    

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生物质热解油的性质精制与利用

朱锡锋,郑冀鲁,郭庆祥,朱清时

《中国工程科学》 2005年 第7卷 第9期   页码 83-88

摘要：

从元素含量、化学成分、稳定性、粘度、热值等方面详细叙述了热解生物油的性质，介绍了生物油的精制和利用技术，其中对近年来出现的生物油热蒸气直接催化精制、利用表面活性剂改良生物油使其直接用于柴油机等新技术给予了特别关注，对催化剂在生物油精制和利用过程中的影响也作了重点叙述。

关键词： 生物质     生物油     燃料特性     精制    

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Challenge of biodiesel production from sewage sludge catalyzed by KOH, KOH/activated carbon, and KOH/

Xuemin Wu,Fenfen Zhu,Juanjuan Qi,Luyao Zhao,Fawei Yan,Chenghui Li

《环境科学与工程前沿（英文）》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0913-y

摘要： The preparation reactions were catalyzed by base solid catalysts. The preparation reactions were catalyzed by two loaded catalysts and KOH. KOH/activated carbon was a better catalyst for biodiesel production. The considerable compounds content, abundance, and low costs involved has led to the proposal to use sewage sludge as raw material for biodiesel production. The transesterification reaction is catalyzed using an acid catalyst instead of base catalysts because of the high free fatty acid concentration. However, the use of a base catalyst, particularly a solid base catalyst, has certain advantages, including faster reaction speed and easier separation. In this study, we utilize in situ transesterification by base catalyst (KOH, KOH/activated carbon (AC) and KOH/CaO) with sewage sludge as raw material. Many conditions have been tested to increase biodiesel yield through single-factor tests, including mass fraction and catalyst dosage. Preliminary experiments have optimized reaction time and temperature. However, the three catalysts did not work better than H SO , which had a maximum yield of 4.6% (dry sewage sludge base) considering the purity by KOH, KOH/CaO, and KOH/AC. The features of the catalyst were analyzed using XRD, BET and SEM. As to BET of KOH/AC and the good spiculate formation of KOH crystal appears to be essential to its function. As for KOH/CaO, the formation of K O and absorption points is likely essential.

关键词： Biodiesel     Sewage sludge     Base catalyst     In situ transesterification    

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Evaluation of endocrine disruption and dioxin-like effects of organic extracts from sewage sludge in

LIU Cao,XU Yiping,MA Mei,HUANG Bingbin,WU Jingdong,MENG Qingyi,WANG Zijian,GEARHEART Robert Alan

《环境科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 433-440 doi: 10.1007/s11783-013-0594-0

摘要： Study on effective disposal and utilization of sewage sludge has recently been the target of growing interest in China. However, potential risks are associated with the use of sludge due to its contamination with toxic organics, heavy metals and pathogenic microorganisms. In this study, a screening assessment was conducted on sewage sludge samples collected from 17 different sewage treatment plants in Beijing, based on a batch of in vitro bioassays, including a set of recombinant gene yeast assays for endocrine disruption, and an ethoxy resorufin-O-deethylase (EROD) assay using H4IIE cells for aryl hydrocarbon receptor (Ah-R) agonistic activities. Our results suggested that moderate levels of estrogen receptor agonistic activities (0.9 ng E2·g to 6.8 ng E2·g , dw), but relative higher androgen receptor antagonistic activities (nd to 45%), progestin receptor antagonistic activities (nd to 80%) and Ah-R agonistic activities (1390 to 6740 pg 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD)·g , dw) were found in sewage sludge samples. However, there were no significant correlations between the toxic effects of sewage sludge and the sewage treatment processes. In addition, the 17β-estradiol (E2) equivalent quantity (EEQ) level of the sewage sludge was increased after the composting treatment, whereas the 2,3,7,8-tetrachlorodibenzo- -dioxin toxic equivalent quantity (TEQ) level of sewage sludge composted was much lower than that of sewage sludge.

关键词： sewage sludge     in vitro bioassay     endocrine disruption     dioxin-like effect    

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Characterization of value-added chemicals derived from the thermal hydrolysis and wet oxidation of sewagesludge

Milan Malhotra, Anurag Garg

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1305-2

摘要： Abstract • Hydrothermal treatment can greatly improve resource recovery from sewage sludge. • tCOD removal during WO was ~55% compared with ~23% after TH. • TOC solubilization during hydrothermal treatment followed first-order kinetics. • Solids and carbon balance confirmed loss of organics during thermal hydrolysis. • Reaction pathways for thermal hydrolysis and wet oxidation are proposed. We evaluated the effect of hydrothermal pretreatments, i.e., thermal hydrolysis (TH) and wet oxidation (WO) on sewage sludge to promote resource recovery. The hydrothermal processes were performed under mild temperature conditions (140°C–180°C) in a high pressure reactor. The reaction in acidic environment (pH= 3.3) suppressed the formation of the color imparting undesirable Maillard’s compounds. The oxidative conditions resulted in higher volatile suspended solids (VSS) reduction (~90%) and chemical oxygen demand (COD) removal (~55%) whereas TH caused VSS and COD removals of ~65% and ~27%, respectively at a temperature of 180°C. During TH, the concentrations of carbohydrates and proteins in treated sludge were 400–1000 mg/L and 1500–2500 mg/L, respectively. Whereas, WO resulted in solids solubilization followed by oxidative degradation of organics into smaller molecular weight carboxylic acids such as acetic acid (~400–500 mg/L). Based on sludge transformation products generated during the hydrothermal pretreatments, simplified reaction pathways are predicted. Finally, the application of macromolecules (such as proteins), VFAs and nutrients present in the treated sludge are also discussed. The future study should focus on the development of economic recovery methods for various value-added compounds.

关键词： Hydrothermal pretreatment     Reaction kinetics     Reaction pathway     Sewage sludge     Thermal hydrolysis     Wet oxidation    

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Recovering humic substances from the dewatering effluent of thermally treated sludge and its performance

Yuning YANG,Huan LI

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 578-584 doi: 10.1007/s11783-015-0827-5

摘要： The biologic treatment of the dewatering effluent from thermally treated sludge is difficult due to the high concentration of refractory humic substances. On the other hand, humic substances are an important source of organic fertilizer. In this study, a novel process using ferric coagulant was developed to recover humic substances from dewatering effluent for use as an organic fertilizer. When ferric coagulant was applied to raw dewatering effluent, up to 70% of humic substances were enmeshed by hydrolyzed ferric ions at an optimum pH of 4.5. The proper mass ratio of iron ions to humic substances was 0.6. In the recovered material, humic substances accounted for 24.2% of the total dry solids, and the amount of phosphorus (equivalent phosphorus pentoxide) was 6.2%. Heavy metals and other components all met the legal requirements for organic fertilizer. When the recovered material was applied to soybeans, the germination and growth of the seeds was significantly improved.

关键词： sewage sludge     humic substances     recovery     phosphorus     fertilizer    

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CFD based combustion model for sewage sludge gasification in a fluidized bed

Yiqun WANG, Lifeng YAN

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 138-145 doi: 10.1007/s11705-009-0050-7

摘要： Gasification is one potential way to use sewage sludge as renewable energy and solve the environmental problems caused by the huge amount of sewage sludge. In this paper, a three-dimensional Computational Fluid Dynamics (CFD) model has been developed to simulate the sewage sludge gasification process in a fluidized bed. The model describes the complex physical and chemical phenomena in the gasifier including turbulent flow, heat and mass transfer, and chemical reactions. The model is based on the Eulerian-Lagrangian concept using the non-premixed combustion modeling approach. In terms of the CFD software FLUENT, which represents a powerful tool for gasifier analysis, the simulations provide detailed information on the gas products and temperature distribution in the gasifier. The model sensitivity is analyzed by performing the model in a laboratory-scale fluidized bed in the literature, and the model validation is carried out by comparing with experimental data from the literature. Results show that reasonably good agreement was achieved. Effects of temperature and Equivalence Ratio (ER) on the quality of product syngas (H + CO) are also studied.

关键词： CFD     model     sewage sludge     gasification     syngas    

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High-solid anaerobic digestion of sewage sludge: achievements and perspectives

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1364-4

摘要：

• High-solid anaerobic digestion (HS-AD) of sewage sludge (SS) is overviewed.

关键词： High-solid effect     Anaerobic fermentation     Methane production     Biodegradability     Sludge treatment    

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Recent advances in the catalytic pyrolysis of biomass

Changwei HU, Yu YANG, Jia LUO, Pan PAN, Dongmei TONG, Guiying LI

《化学科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 188-193 doi: 10.1007/s11705-010-1015-6

摘要： Biomass is considered as a renewable and alternative resource for the production of fuels and chemicals, since it is the only carbon and hydrogen containing resource that we can find in the world except for fossil resources, capable of being converted to hydrocarbons. The pyrolytic liquefaction of biomass is a promising way to convert biomass to useful products. This paper briefly surveys the present status of the direct catalytic pyrolysis for the liquefaction of biomass. The direct use of catalysts could decrease the pyrolysis temperature, increase the conversion of biomass and the yield of bio-oil, and change the distribution of the pyrolytic liquid products then improve the quality of the bio-oil obtained. The fact that biomass is in solid state present great challenges for its conversion and for the effective use of catalysts due to the bad heat transfer characteristics and bad mass transfer properties. These barriers appeal for the development of a new catalyst and new catalytic process as well as the integration of both. Process design and process intensification are of significant importance in the catalytic conversion of biomass.

关键词： biomass     liquefaction     catalysis     bio-oil     process intensification    

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Properties and effect of forming sewage sludge into lightweight ceramics

Min YUE, Qinyan YUE, Yuanfeng QI, Baoyu GAO, Hui YU

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 117-124 doi: 10.1007/s11783-010-0220-3

摘要： In this work we investigated the chemical, thermal and toxic properties of dried sewage sludge (DSS), the preparation and properties of lightweight sludge ceramic (LSC) and the mechanisms of action of the organic and inorganic foaming agents (OFAs and IFAs). The chemical components and thermal properties of the raw materials were studied by Energy Dispersive X-ray Detection (EDX) and Thermogravimetric Analysis and Differential Scanning Calorimetry (DSC/TGA). The mineral phases of the raw materials and the formed ceramics were determined by X-ray Diffraction (XRD). The leaching characteristics of heavy metals were investigated with Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). Different ratios of DSS and clay were mixed and pressed into raw pellets. After drying and preheating treatment, the raw pellets were sintered at 1150°C for 10 min. The physical properties of LSC (50 wt% DSS added) were tested. The results showed that when the addition of DSS was above 50 wt%, LSC began to shrink, and a maximum density occurred. The environmental safety of LSC was satisfactory. XRD showed that some new mineral phases formed in the LSC. Observation of the microstructure by Scanning Electron Microscope (SEM) indicated that the body of LSC was porous.

关键词： sludge     foaming agents     ceramics     preheating process    

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Biodegradation of triclosan and triclocarban in sewage sludge during composting under three ventilation

Bao Yu, Guodi Zheng, Xuedong Wang, Min Wang, Tongbin Chen

《环境科学与工程前沿（英文）》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1125-4

摘要：

TCS and TCC can be biodegraded during sewage sludge composting.

Ventilation significantly accelerated the biodegradation of TCS and TCC in sludge.

Composting can reduce the environmental risk of TCS and TCC in sewage sludge.

关键词： Sewage sludge     Compost     Triclosan     Triclocarban     Ventilation     Risk assessment    

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标题 作者 时间 类型 操作

Research on combustion characteristics of bio-oil from sewage sludge

Rui LI, Baosheng JIN, Xiangru JIA, Zhaoping ZHONG, Gang XIAO, Xufeng FU

期刊论文

Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

期刊论文

生物油的蒸馏特性及其应用

杨续来,陆　强,朱锡锋

期刊论文

Design of bio-oil additives via molecular signature descriptors using a multi-stage computer-aided molecular

期刊论文

A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

期刊论文

生物质热解油的性质精制与利用

朱锡锋,郑冀鲁,郭庆祥,朱清时

期刊论文

Challenge of biodiesel production from sewage sludge catalyzed by KOH, KOH/activated carbon, and KOH/

Xuemin Wu,Fenfen Zhu,Juanjuan Qi,Luyao Zhao,Fawei Yan,Chenghui Li

期刊论文

Evaluation of endocrine disruption and dioxin-like effects of organic extracts from sewage sludge in

LIU Cao,XU Yiping,MA Mei,HUANG Bingbin,WU Jingdong,MENG Qingyi,WANG Zijian,GEARHEART Robert Alan

期刊论文

Characterization of value-added chemicals derived from the thermal hydrolysis and wet oxidation of sewagesludge

Milan Malhotra, Anurag Garg

期刊论文

Recovering humic substances from the dewatering effluent of thermally treated sludge and its performance

Yuning YANG,Huan LI

期刊论文

CFD based combustion model for sewage sludge gasification in a fluidized bed

Yiqun WANG, Lifeng YAN

期刊论文

High-solid anaerobic digestion of sewage sludge: achievements and perspectives

期刊论文

Recent advances in the catalytic pyrolysis of biomass

Changwei HU, Yu YANG, Jia LUO, Pan PAN, Dongmei TONG, Guiying LI

期刊论文

Properties and effect of forming sewage sludge into lightweight ceramics

Min YUE, Qinyan YUE, Yuanfeng QI, Baoyu GAO, Hui YU

期刊论文

Biodegradation of triclosan and triclocarban in sewage sludge during composting under three ventilation

Bao Yu, Guodi Zheng, Xuedong Wang, Min Wang, Tongbin Chen

期刊论文